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Title: FISCHER-TROPSCH SYNTHESIS OVER POLYMER SUPPORTED PROMOTED IRON CATALYSTS
FISCHER-TROPSCH SYNTHESIS OVER POLYMER SUPPORTED PROMOTED IRON CATALYSTS

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Mariia E. Markova; Antonina A. Stepacheva; Vladimir P. Molchanov; Galina N. Demidenko; Mikhail G. Sulman
10.5593/sgem2024/4.1/s17.12
10.5593/sgem2024/4.1
1314-2704
978-619-7603-71-2
English
24
4.1
•    Prof. DSc. Oleksandr Trofymchuk, UKRAINE 
•    Prof. Dr. hab. oec. Baiba Rivza, LATVIA
17.Renewable Energy Sources and Clean Technologies
In recent decades, the interest of researchers has focused on the development of methods for obtaining alternative energy sources. Fischer-Tropsch synthesis is one of the methods for obtaining a wide range of hydrocarbons and their derivatives. Ru, Ni, Fe and Co are the widely used catalytically active metals in FTS. To increase the activity of the catalyst, as well as increase the yield of target products, promoters are introduced into catalytic systems. In FTS, oxides of alkaline and rare earth metals, oxides of lanthanides and actinides, and noble metals are used as modifiers.
In this work, we studied the effect of Fe promotion with Ni, Co, and Ru on the CO conversion and the formation of gasoline-range hydrocarbons in the liquid-phase FTS. Novel catalysts supported on the aromatic polymer matrix characterized by the high specific surface area and fine distribution of the active phase were developed. The addition of Ru to the Fe catalyst was shown to increase both CO conversion and selectivity toward the formation of gasoline-range alkanes compared to the monometallic catalysts.
[1] The auditors explained the decrease in the share of oil and gas budget revenues to a minimum. Sanctions have not become the main factor in such dynamics / Economics, 2023 / URL: https://www.rbc.ru/economics/23/11/2023/655dcfa69a79471d752b6f80 (in Russian).
[2] Kurakin V.I., Abramchikova N.V. Analysis of the peculiarities of the formation of the structure of the Russian oil and gas industry / Economic Sciences, Russia, vol. 2/issue 195, pp. 101 – 108, 2021 (in Russian).
[3] Fry M.E. Assessment of the current state of the Russian oil industry // Bulletin of the Udmurt University of Economics and Law, Russia, vol. 25 /issue 2. pp. 75-85, 2015 (in Russian).
[4] Russia is provided with proven oil reserves of the fields under development, excluding TRIZ, for no more than 20 years / URL: http://www.Neftegaz.ru . (in Russian).
[5] Discoveries of the year: new fields in Russia and the world / Drilling and Oil, 2016.URL: http://burneft.ru/main/news/15958. (in Russian).
[6] Sinyak Yu.V. Economic assessment of the potential of world oil and gas reserves // Problems of forecasting, Russia, vol. 6, pp. 86-107, 2015(in Russian).
[7] Muslimov R.H. A new classification of reserves and resources of oil and combustible gases – moving forward or backward? // Geo resources, Russia, vol. 18. /issue 2, pp. 80-87, 2016 (in Russian).
[8] Berezina E. Is there a life without oil? // Rossiyskaya Gazeta - Federal issue, Russia, vol. 55 /issue.6923, pp. 5, 2016 (in Russian).
[9] A review of advanced catalyst development for Fischer–Tropsch synthesis of hydrocarbons from biomass derived syn-gas / H. Jahangiri, J. Bennett, P. Mahjoubi, K. Wilson, S. Gu // Catal. Sci. Technol. Vol. 4, pp. 2210-2229, 2014.
[10] Bimetallic synergy in cobalt ruthenium Fischer-Tropsch synthesis catalysts / E. Iglesia, S.L. Soled, R.A. Fiato, G.H. Via // J. Catal. Vol. 143, pp. 345-368, 1993.
[11] Raje A., O'Brien R.J., Davis B.H. Effect of potassium promotion on iron-based catalysts for Fischer-Tropsch synthesis // J. Catal. Vol. 180/issue.1, pp. 36-43, 1998.
[12] Fischer-Tropsch synthesis: activity and selectivity for group I alkali promoted iron-based catalysts / W. Ngantsoue-Hoc, Y.Q. Zhang, R.J. O'Brien, M.S. Luo, B.H. Davis // Appl. Catal. A. Vol. 236, pp. 77–89, 2002.
[13] Slurry phase Fischer-Tropsch synthesis over manganese-promoted iron ultrafine particle catalyst / L. Bai, H. W. Xiang, Y. W. Li, Y. Z. Han, B. Zhong // Fuel. Vol. 81, pp. 1577–1581, 2002.
[14] Design, Synthesis, Site Densities, and Catalytic Properties / S. Li, S. Krishnamoorthy, A. Li, G.D. Meitzner, E. Iglesia // J. of Catalysis. Vol. 206, pp. 202–217, 2002.
[15] Liuzzi D., P?erez-Alonso F.J., Rojas S. Full Length Article Ru-M (M = Fe or Co) Catalysts with high Ru surface concentration for Fischer-Tropsch synthesis //Fuel. Vol. 293, pp. 120435 – 120460, 2021.
[16] Investigating the Stability of Ru-promoted Fe-based Fischer-Tropsch Catalyst at high Synthesis Gas Conversion / I. Fraser, A.M. Rabiu, E. van Steen // Energy Procedia, vol. 100, pp. 210 – 216, 2016.
[17] Enhancement of the catalytic performance of silica nanosprings (NS)-supported iron catalyst with copper, molybdenum, cobalt and ruthenium promoters for Fischer-Tropsch synthesis / A. Alayat, E. Echeverria, D N. Mcllroy, A.G. McDonald // Fuel Processing Technology, vol. 177, pp.89–100, 2018.
[18] Insights to the reaction kinetics of Fischer-Tropsch synthesis using an integral system over Cu-Mo promoted Fe catalyst / Z. Teimouri, N. Abatzoglou, A.K. Dalai// Fuel, vol. 360, pp. 130512, 2024.
[19] Study on an iron–nickel bimetallic Fischer–Tropsch synthesis catalyst / T. Li, H. Wang, Y. Yang, H.Xiang, Y. Li // Fuel Processing Technology, vol. 118, pp. 117-124, 2014.
[20] M?Fe, Zn, Ni and Co) nanoparticles: Facile synthesis approach and their superb stability and catalytic performance in Fischer-Tropsch synthesis / M. Abbas, J. Zhang, T.S. Mansour, J. Chen // International journal of hydrogen energy, vol. 45, pp. 10754 – 10763, 2020.
The work is financially supported by the Russian Science Foundation (grant 23-23-00653).
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https://doi.org/10.5593/sgem2024/4.1/s17.12
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Proceedings of 24th International Multidisciplinary Scientific GeoConference SGEM 2024
24th International Multidisciplinary Scientific GeoConference SGEM 2024, 1 - 7 July, 2024
Proceedings Paper
STEF92 Technology
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SWS Scholarly Society; Acad Sci Czech Republ; Latvian Acad Sci; Polish Acad Sci; Russian Acad Sci; Serbian Acad Sci and Arts; Natl Acad Sci Ukraine; Natl Acad Sci Armenia; Sci Council Japan; European Acad Sci, Arts and Letters; Acad Fine Arts Zagreb Croatia; Croatian Acad Sci and Arts; Acad Sci Moldova; Montenegrin Acad Sci and Arts; Georgian Acad Sci; Acad Fine Arts and Design Bratislava; Russian Acad Arts; Turkish Acad Sci.
99-106
1 - 7 July, 2024
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Fischer-Tropsch synthesis, hydrocarbons, iron-containing catalysts, polymer support

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