Peer-reviewed articles 17,970 +



Title: SOLID RESIDUES FROM THE COBUSTION OF BIOMASS – HEAVY METALS CONTAMINATION AND POSSIBLE REUSE

SOLID RESIDUES FROM THE COBUSTION OF BIOMASS – HEAVY METALS CONTAMINATION AND POSSIBLE REUSE
Milena Pavlikova; Martina Zaleska; Jana Nabelkova; Adam Pivak; Zbysek Pavlik
10.5593/sgem2024/6.1
1314-2704
English
24
6.1
•    Prof. DSc. Oleksandr Trofymchuk, UKRAINE 
•    Prof. Dr. hab. oec. Baiba Rivza, LATVIA
This manuscript presents the comprehensive chemical and physical analysis of two types of biomass ashes derived from power and heat generation in order to highlight their positive parameters and properties and to propose the way for their safe reuse in the production of building materials. The analysis of biomass ashes included the assessment of chemical composition, dry matter content, loss on ignition, particle size distribution, Blaine fineness, dry powder density, specific density, pozzolanic activity, SEM morphology and microstructure. Emphasis was placed on the analysis of heavy metals content. The results of comprehensive physical and chemical tests proved the potential use of the investigated biomass ashes in the production of construction materials in the form of active component of blended binders or mineral fillers, while ensuring safe disposal of environmentally hazardous waste from energy production. Thus, it will be possible design and develop new eco-efficient materials with low carbon footprint enabling heavy metals stabilization and immobilization.
[1] Wang, L., Gi, T., Feng, G., Wang, Z., Wang, H., Han, Y., He, J., Du, S., Li, K., He, J., Green utilization of biomass by-product poplar leaf ash: A novel eco-friendly cementitious material for cement mortar replacement, Construction and Building Materials, vol. 393, 132025, 2023.
[2] Zhao, X., Zhu, H., Sikerwar, V.S., Zhao, M., Partk, A.-H.A., Fenell, P.S., Shen, L., Fan, L.-S., Biomass-based chemical looping technologies: the good, the bad and the future, Energy and Environmental Science, vol. 10, 1885, 2017.
[3] Carrasco, B., Cruz, N., Terrados, J., Corpas, F.A., P?erez, L., An evaluation of bottom ash from plant biomass as a replacement for cement in building blocks, Fuel, vol. 118, pp. 272–280, 2014.
[4] Katare, V.D., Madurwar, M.V., Experimental characterization of sugarcane biomass ash – a review, Construction and Building Materials, vol. 152, pp. 1-15, 2017.
[5] Tekin, I., Dirikolu, I., Gokce, H.S., A regional supplementary cementitious material for the cement industry: Pistachio shell ash, Journal of Cleaner Production, vol. 285, 124810, 2021.
[6] Martinez-Lage, I., Velay-Lizancos, M., Vazquez-Burgo, P., Rivas-Fernandez, M., Vazquez-Herrero, C., Ramirez-Rodriguez, A., Martin-Cano, M., Concretes and mortars with waste paper industry: Biomass ash and dregs, Journal of Environmental Management, vol. 181, pp. 863–873, 2016.
[7] Tosti, L., van Zomeren, A., Pels, J.R., Dijkstra, J.J., Comans, R.N.J., Assessment of biomass ash applications in soil and cement mortars, Chemosphere, vol. 223, pp. 425–437, 2019.
[8] Athira, G., Bahurudeen, A., Rheological properties of cement paste blended with sugarcane bagasse ash and rice straw ash, Construction and Building Materials, vol. 332, 127377, 2022.
[9] Castillo, D., Cruz, J.C., Trejo-Arroyo, D.L., Muzquiz, E.M., Zarhri, Z. Gurrola, M.P., Vega-Azamar, R.E., Characterization of poultry litter ashes as a supplementary cementitious material, Case Studies in Construction Materials, vol. 17, e01278, 2022.
[10] Pavlik, Z., Zaleska, M., Pavlikova, M., Pivak, A., Nabelkova, J., Jankovsky, O., Jirickova, A., Chmel, O., Prusa, F., Simultaneous immobilization of heavy metals in MKPC-based mortar—Experimental assessment, Materials, vol. 16, 7525, 2023.
[11] EN 15169, Soil, waste, treated biowaste and sludge – Determination of loss on ignition, European Committee for Standardization (CEN), Brussels, Belgium, 2021.
[12] EN 196-6, Methods of testing cement –
Part 6: Determination of fineness, European Committee for Standardization (CEN), Brussels, Belgium, 2018.
[13] Zaleska, M., Pavlikova, M., Pavlik, Z., Classification of a-SiO2 rich materials, Materials Science Forum, vol. 824, pp. 33-38, 2015.
[14] NF P 18-513, Pozzolanic Addition for Concrete – Metakaolin. Definitions, Specifications and Conformity Criteria. Annex A., AFNOR, La Plaine Saint-Denis, France, 2009.
[15] EN 450-1, Fly ash for concrete - Part 1: Definition, specifications and conformity criteria, European Committee for Standardization (CEN), Brussels, Belgium, 2012.
[16] ASTM C618 – 19, Standard Specification for Coal Fly Ash and Raw Calcined Natural Pozzolan for Use in Concrete, ASTM International, West Conshohocken, PA, United States, 2019.
[17] 273/2021 Sb., Vyhlaska o podrobnostech nakladani s odpady (in Czech), Annex 5, available online at: https://www.zakonyprolidi.cz/cs/2021-273 (accessed February 5, 2024).
Authors greatly acknowledge the financial support received from the Czech Science Foundation under project No. 23-04744S - Research of heavy metals immobilization in alternative low-carbon composites. The scholarship of A. Pivak has been partially supported by the Grant Agency of the Czech Technical University in Prague, grant No. SGS23/OHK1/3T-002/23 - Research and development of high performance building composites.
conference
Proceedings of 24th International Multidisciplinary Scientific GeoConference SGEM 2024
24th International Multidisciplinary Scientific GeoConference SGEM 2024, 1 - 7 July, 2024
Proceedings Paper
STEF92 Technology
International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM
SWS Scholarly Society; Acad Sci Czech Republ; Latvian Acad Sci; Polish Acad Sci; Russian Acad Sci; Serbian Acad Sci and Arts; Natl Acad Sci Ukraine; Natl Acad Sci Armenia; Sci Council Japan; European Acad Sci, Arts and Letters; Acad Fine Arts Zagreb Croatia; Croatian Acad Sci and Arts; Acad Sci Moldova; Montenegrin Acad Sci and Arts; Georgian Acad Sci; Acad Fine Arts and Design Bratislava; Russian Acad Arts; Turkish Acad Sci.
295-302
1 - 7 July, 2024
website
9810
biomass ash, safe disposal, health and environmental risks, leachability of heavy metals, pozzolanic activity, ash classification

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