Peer-reviewed articles 17,970 +



Title: RECOVERY OF LITHIUM AND DESALTED WATER FROM OILFIELD BRINE

RECOVERY OF LITHIUM AND DESALTED WATER FROM OILFIELD BRINE
Ewa Knapik; Grzegorz Rotko
10.5593/sgem2024/1.1
1314-2704
English
24
1.1
•    Prof. DSc. Oleksandr Trofymchuk, UKRAINE 
•    Prof. Dr. hab. oec. Baiba Rivza, LATVIA
Oilfield brine extracted with hydrocarbons is often considered as a problematic waste. The typical management option for this produced water is reinjection into the formation to maintain the reservoir pressure (or just for disposal). High salinity of produced water is on the one hand a drawback, but on the other hand an advantage because it can be used as a raw material for the production of valuable chemicals. In this paper a freezing-thawing desalination method was tested to obtain partially desalted water and concentrated brine from produced water. The obtained desalted water with conductivity lower than 10 mS/cm could be beneficially reuse for non-potable applications (crop irrigation, livestock watering). The concentrate with conductivity above 80 mS/cm is a suitable feed for salt/chemicals production. As the lithium content in the obtained concentrate was high, up to 20 mg/L, so the Mn-based sorbent was applied to recover it. The lithium-selective sorbent was prepared via solid state reaction and its morphological and textural parameters confirm its good chemical stability and high affinity towards lithium ions. The lithium recovery ration in static conditions was above 95 %. The obtained results prove that produced water may be beneficially reuse outside the energy sector.
[1] Clark C. E., Veil J. A., Produced water volumes and management practices in the United States. Argonne National Laboratory (ANL), Oak Ridge, 2009.
[2] Jiang W., Lin L., Xu X., Wang H., Xu P., Analysis of regulatory framework for produced water management and reuse in major oil- and gas-producing regions in the United States, Water, vol. 14, no. 14. 2022, https://doi.org/10.3390/w14142162.
[3] Dolan F. C., Cath T. Y., Hogue T. S., Assessing the feasibility of using produced water for irrigation in Colorado, Science of the Total Environment, vol. 640–641, pp. 619–628, 2018, https://doi.org/10.1016/j.scitotenv.2018.05.200.
[4] Recycled oilfield produced water program, available online: https://www.cawelowd.org/recycled-produced-water (accessed on 24 Juni 2024).
[5] McCurdy, R., 2011, Underground injection wells for produced water disposal, Proceedings of the Technical Workshops for the Hydraulic Fracturing Study: Water Resources Management, available online: https://www.epa.gov/sites/default/files/ documents/HF_Workshop_4_Proceedings_FINAL_508.pdf (accessed on 24 Juni 2024).
[6] Mallants D., Simunek J., Torkzaban S., Determining water quality requirements of coal seam gas produced water for sustainable irrigation,” Agricultural Water Managment, vol. 189, pp. 52–69, 2017, https://doi.org/10.1016/j.agwat.2017.04.011
[7] Jaffar S., Khaliq A., Ahmed M., Al-Wardy M., Al-Busaidi A., Choudri B. S., Wastewater and sludge management and research in Oman: An overview, Journal of the Air & Waste Management Association, vol. 67, no. 3, pp. 267–278, 2017, https://doi.org/10.1080/10962247.2016.1243595.
[8] Miranda M. A., Ghosh A., Mahmodi G., Xie, S., Shaw M., Kim S., Krzmarzick M .J., Lampert D. J., Aichelle C. P., Treatment and recovery of high-value elements from produced water, Water, vol. 14, no. 6. 2022, https://doi.org/10.3390/w14060880.
[9] Shaffer D. L., Arias Chavez L. H., Ben-Sasson M., Romero-Vargas Castrillon S., Yip N. Y., Elimelech M., Desalination and reuse of high-salinity shale gas produced water: drivers, technologies, and future directions, Environmental Science & Technology, vol. 47, no. 17, pp. 9569–9583, 2013, https://doi.org/10.1021/es401966e.
[10] Ricceri F., Giagnorio M., Farinelli G., Blandini G., Minella M., Vione D., Tiraferri A., Desalination of produced water by membrane distillation: effect of the feed components and of a pre- treatment by Fenton oxidation, Scientific Reports, vol. 9, pp. 1–12, 2019, https://doi.org/10.1038/s41598-019-51167-z.
[11] Ozgun H. et al., Effects of the pre-treatment alternatives on the treatment of oil-gas field produced water by nanofiltration and reverse osmosis membranes, Journal of Chemical Technology and Biotechnology, vol. 88, no. 8, pp. 1576–1583, 2013, https://doi.org/10.1002/jctb.4007.
[12] Najim A., A review of advances in freeze desalination and future prospects, npj Clean Water, vol. 5, no. 1, p. 15, 2022, https://doi.org/10.1038/s41545-022-00158-1.
[13] Noor Akashah M. H., Mohammad Rozali N. E., Mahadzir S., Liew P. Y., Utilization of cold energy from LNG regasification process: a review of current trends, Processes, vol. 11, no. 2, 2023, https://doi.org/10.3390/pr11020517.
[14] Rotko G., Knapik E., Piotrowski M., Marszalek M., Oilfield brine as a source of water and valuable raw materials—proof of concept on a laboratory scale, Water, vol. 16, no. 11, 2024, https://doi.org/10.3390/w16111461.
[15] What is the typical water conductivity range?, 2022, available online: https://atlas-scientific.com/blog/water-conductivity-range/ (accessed on 24 Juni 2024).
The research leading to these results has received funding from the National Centre for Research and Development (NCBR) in the frame of Project Contract No. LIDER/34/0174/L-12/20/NCBR/2021 under the LEADER Program.
conference
Proceedings of 24th International Multidisciplinary Scientific GeoConference SGEM 2024
24th International Multidisciplinary Scientific GeoConference SGEM 2024, 1 - 7 July, 2024
Proceedings Paper
STEF92 Technology
International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM
SWS Scholarly Society; Acad Sci Czech Republ; Latvian Acad Sci; Polish Acad Sci; Russian Acad Sci; Serbian Acad Sci and Arts; Natl Acad Sci Ukraine; Natl Acad Sci Armenia; Sci Council Japan; European Acad Sci, Arts and Letters; Acad Fine Arts Zagreb Croatia; Croatian Acad Sci and Arts; Acad Sci Moldova; Montenegrin Acad Sci and Arts; Georgian Acad Sci; Acad Fine Arts and Design Bratislava; Russian Acad Arts; Turkish Acad Sci.
441-448
1 - 7 July, 2024
website
9884
brine, oilfield, desalination, freezing-thawing, lithium recovery

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